I'm pretty sure the microcontroller in the SYNC module only supports USB On-The-Go (OTG), which is the cause of the hub issues. The complete explanation of OTG can be found at
this link. However, if you don't want to click through, the relevant excerpt is below:
"USB On-The-Go does not preclude using a USB hub,
but it describes Host/Peripheral role swapping only for the case of a
one-to-one connection where two OTG devices are directly connected. If
a standard hub is used, the supplement notes that using it will lead to
losing USB OTG role-swap capabilities, locking one device as the Host
and the other as the Peripheral until the hub is disconnected."
And since SYNC locks to a single device (i.e., one of your media devices on the hub), the others are not accessible.